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Of the acylation of aliphatics, the acylation of alkenes pioneered by Nenitzescu was mainly explored, because the resulting unsaturated ketones are intermediates in synthesis. This acylation of alkenes, however, has its difficulties. First, the product unsaturated ketones, which are reactive compounds themselves, can undergo various further transformations, such as addition, elimination, and isomerization, often resulting in complex product mixtures. The acylation of alkenes, therefore, is less selective and often yields products other than expected by a simple substitution of one of the vinylic hydrogens. The frequent and sometimes exclusive formation of ~,y-unsaturated ketones was long an intriguing aspect of the Friedel-Crafts acylation of alkenes. 11 ,13 In fact, it is often found that the more stable cx,~-unsaturated ketone is produced by isomerization of the initially formed nonconjugated isomer. This can be understood by the carbocationic mechanism as shown in Eq. (8.10). The reaction is interpreted to proceed through 15 the most stable ~-keto carbocationic intermediate. The loss of a proton usually results in the nonconjugated unsaturated ketone that is formed by a [1,5] hydrogen shift followed by an enol-oxo tautomerization. Because of the lack of driving force for rearomatization by a proton loss, as is the case in acylation of aromatics, the intermediate carbocation may stabilize by reacting with the halide of the acid halide reagent, often leading to the formation of ~-halo ketones [Eq. (8.11)]:

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Cummulative percentage (%) 100 Samples (%) 100 95 90 85 80 75 70 65 60 0 10

Command About Fireworks Keyboard Shortcuts Preferences Services Hide Fireworks Hide Others Show All Quit Fireworks Description Displays the About Fireworks dialog box with information about the application and its authors Displays the Keyboard Shortcuts dialog box, which enables you to modify keyboard shortcuts Displays the Preferences dialog box where you set user preferences Displays a submenu of available system services Hides the Fireworks application and all of its windows Hides all running applications except for Fireworks Shows all running applications Quits the Fireworks application Keystroke n/a n/a Command+U n/a Command+H n/a n/a Command+Q

Single-port RAM with synchronous read The template for the single-port RAM with synchronous read is shown in Listing 11.2. It is modified after the rams-07 entity of the XST Manual.

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<xsl:choose> <xsl:when test= $format= rss > <xsl:call-template name= rss20.entry > <xsl:with-param name= entry.title select= $entry.title /> <xsl:with-param name= entry.id select= $entry.id /> <xsl:with-param name= entry.date select= $entry.date /> <xsl:with-param name= entry.summary select= $entry.summary /> <xsl:with-param name= entry.link select= $entry.link /> </xsl:call-template> </xsl:when> <xsl:otherwise> <xsl:call-template name= atom03.entry > <xsl:with-param name= entry.title select= $entry.title /> <xsl:with-param name= entry.id select= $entry.id /> <xsl:with-param name= entry.date select= $entry.date /> <xsl:with-param name= entry.summary select= $entry.summary />

The FXG 2 specification includes updates, name changes, and a few extra properties in various elements and attributes. Adobe decided to make version 2 a full revision rather than a 1.x maintenance release because the CS4 products already support FXG 1.0. A full version-number update ensures that each version of the Creative Suite product can easily tell whether it s working with a version it understands. n

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Byzantine failure: In this model, a processor fails by exhibiting arbitrary behavior. This is an extreme form of a failure. A system that can tolerate a Byzantine fault can tolerate any other fault.

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Fireworks places a separator in the History panel (also shown in Figure 19-13) when you change your selection. Replaying steps across a separator can have unpredictable results because some objects can t be modified in the same way as other objects.

If you work with a number of graphics applications, you may find working with your operating system s color picker(s) rather than with those in Fireworks is more convenient. To open the system color picker(s), click the Palette button on the Fireworks color picker. Closing the system color picker(s) automatically assigns the last selected color to the Fireworks color well. The Macintosh system color picker dialog box has several color pickers from which to choose. Table 7-2 details these different schemes.

Color in the natural world comes at us full force, without any impediments. Color on the Web, however, passes through many filters. At the most basic level, the computer dictates how color is generated. Rather than using a system of blending inks as with print, the computer blends light red, green, and blue light, to be precise. Next, the color settings and capability of a viewer s specific system determine the range of colors to be used. The final filter for Web-based color is the browser, in all of its varied configurations and versions.

n direct mail.xlsx: A workbook that contains a profit model to demonstrate how to create a 2-way data table for what-if analysis. n mortgage loan data table.xlsx: A workbook that demonstrate how to create a data 1-way data table for what-if analysis. n mortgage loan.xlsx: A workbook with input cells and formula cells to demonstrate what-if analysis. n production model.xlsx: A workbook to demonstrate the Scenario Manager.

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